Organic Chemistry

Introduction of Inductive Effect

In the organic compound molecule, due to the influence of different electronegativity substituents (atoms or atomic groups), the density of the bonding electron cloud in the whole molecule is shifted in a certain direction, and the effect of polarization of the molecule is called an Induction effect. Inductive Effect

What are Inductive Effects?

The induced effect exhibited by the polar bond is called the Static induction effect, and the induced effect caused by the polarization bond generated by the influence of the external electric field (such as reagent, solvent) during the chemical reaction is called the dynamic induction effect.

The inductive effect only changes the electron cloud density distribution within the bond without changing the nature of the bond. And compared with the conjugate effect, there is no polarity alternation.

Let me explain about Inductive effect.

  1. A covalent bond is formed by sharing of electrons

H … H  —->   H–H

  1. If similar atom involves electron pair remain in the middle

H  -:-  H

  1. If dissimilar atom involves electron pair shifted towards a more electronegative atom.

H -:- Cl     =>    +H -:- Cl-

Inductive Effect

Definition of Inductive Effect:-

  • Shifting of electrons in covalent bond from low electronegative atom to high electronegative atom
  • Always sigma (a) electrons are displaced (only occur in single bond)
  • It is a permanent effect
  • It is distance dependent (decrease when the distance is an increase)
  • It is two types which depend on the type of group attached.

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Basic nature

The Induction effect is characterized by an electron cloud shift that is transmitted along with the σ bond and weakens as the carbon chain grows, eventually disappearing.

The inductive effect is a short-range force that is already weak when passed to the third carbon and almost completely disappears when it reaches the fifth carbon.

The inductive effect is an electrostatic effect that is permanent and belongs to one of the electronic effects.

Display method:

In the induction effect, the arrow “→” is generally used to indicate the direction in which the electron moves, indicating that the distribution of the electron cloud has changed.

For example, after the chlorine atom has replaced the hydrogen atom on the alkane carbon, as shown below:

Since chlorine has a large electronegativity, the ability to attract electrons is strong, and electrons shift to chlorine, causing a partial negative charge (δ  ) of the chlorine band and a partial positive charge (δ + ) of the carbon band.

The partially positively charged carbon, in turn, attracts electrons on adjacent carbons, causing them to shift.

Types of Induction Effect:

Static induction effect: The inherent nature of static molecules due to the presence of polar covalent bonds in the molecule (intrinsic electric field).

The effect on the reactivity of the compound has two-sidedness, and under certain conditions, the reactivity may be increased, and the reactivity may be lowered.

Dynamic induction effect occurs when a chemical reaction occurs due to the appearance of an external electric field. Usually, only at the moment of the chemical reaction, the role played is to accelerate the reaction.

Induction Effect Index:

A quantitative measure of chemical activity.

For example

-CHO (aldehyde group)

-OH (alcohol group)

-CO (ketone group)

-NH2 (Amino group)

-CN (cyanide group)

-COOH (carboxyl group)

Electron donating groups

+I effecting group

All alkyl Groups show this effect.

For example

-CH3 (methyl group)

-C2H5 (ethyl group)

-CH (CH3)2 (isopropyl group)

-C (CH3)3 (tertiary butyl group)


Inductive Effect

Application of Inductive Effect

  1. Stability of carbonation
  2. Stability of Carbanion
  3. Stability of Free radicals
  4. The acidity of the carboxylic acid
  5. Basicity of amines

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